Sodium Hydroxide

Sodium Hydroxide

Strong alkalinity: Sodium hydroxide is a highly corrosive strong alkali. A 1% aqueous solution has a pH of 12.7. It can neutralize acids to produce salt and water, making it a highly efficient neutralizing agent and pH adjuster.


Strong hygroscopicity and deliquescentness: Sodium hydroxide is highly hygroscopic, readily absorbing water vapor from the air and deliquescing. It also absorbs acidic gases such as carbon dioxide, a property that makes it suitable as an alkaline desiccant.


Excellent solubility and exothermic properties: Sodium hydroxide is readily soluble in water, with solubility increasing significantly with increasing temperature (418 g/L at 0°C, 1110 g/L at 20°C, and 3370 g/L at 100°C). Dissolution releases a large amount of heat; therefore, safety precautions must be taken when using it.


High reactivity: Sodium hydroxide reacts with amphoteric metals such as aluminum and zinc, as well as non-metals such as boron and silicon, releasing hydrogen gas; it undergoes disproportionation reactions with halogens such as chlorine, bromine, and iodine; it reacts with various metal salts to form hydroxide precipitates; and it undergoes saponification reactions with oils and fats.


Strong corrosiveness: Sodium hydroxide is highly corrosive to fibers, skin, glass, and ceramics. Protective goggles and rubber gloves must be worn during handling. If it comes into contact with skin, immediately flush with plenty of water.


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Product Description

Sodium Hydroxide Product Description CAS#1310-73-2


Sodium hydroxide, commonly known as caustic soda, lye, flake caustic soda, or caustic alkali, has the chemical formula NaOH and a molecular weight of 40.01. At room temperature, it is a white, semi-transparent crystalline solid. Common commercial forms include flakes, granules, lumps, and liquid. Its melting point is 318.4°C, boiling point is 1390°C, and density is 2.13 g/cm³. In terms of solubility, sodium hydroxide is readily soluble in water (solubility of 1110 g/L at 20°C), releasing a large amount of heat upon dissolution; it is also soluble in ethanol and glycerol, but insoluble in acetone and ether. Sodium hydroxide is highly hygroscopic, readily deliquescing in air, and can absorb acidic gases such as carbon dioxide. Industrially, sodium hydroxide is mainly produced by electrolysis in the chlor-alkali industry, using a saturated sodium chloride solution as raw material, through ion exchange membrane or diaphragm electrolysis; it can also be produced using traditional processes such as the soda ash causticization method. Sodium hydroxide is one of the most basic chemical raw materials. As an important member of the "three acids and two alkalis" group, its strong alkalinity, high reactivity, and wide compatibility make it irreplaceable and fundamental in many sectors of the national economy, including chemical, papermaking, textile, metallurgy, food, pharmaceutical, and environmental protection industries.


Sodium Hydroxide Product Applications CAS#1310-73-2


Sodium hydroxide is one of the most important basic chemical raw materials, widely used in hundreds of industries including chemical, papermaking, textile, metallurgy, food, pharmaceutical, petroleum, environmental protection, and daily chemicals.


Product Forms and Specifications: Sodium hydroxide products are divided into two main categories: liquid and solid. Common concentrations of liquid sodium hydroxide are 32% and 48%; solid sodium hydroxide is available in flakes and granules. Products cover industrial and food grades. Industrial-grade sodium hydroxide conforms to the national standard GB/T 209-2018 and is widely used in papermaking, soap making, textile, printing and dyeing, chemical fiber, pesticide, metallurgy, petrochemical, fine chemical, and power industries. Food-grade sodium hydroxide is mainly used as an acid-base adjuster and can also be used in cosmetics manufacturing.


Chemical Industry: Sodium hydroxide is an important raw material for manufacturing organic and inorganic chemicals such as formic acid, oxalic acid, borax, phenol, and sodium cyanide; it is used in the production of soap, synthetic detergents, synthetic fatty acids, and the refining of animal and vegetable oils; it is also used in the production of smelting products such as alumina.


Product Information

Chemical Properties

PropertyValue
Melting point

681 °C(lit.)

Boiling point

1390°C

Density

1.515 g/mL at 20 °C

Vapor Density

<1 (vs air)

Vapor Pressure

1 mm Hg ( 745 °C)

Refractive index

1,473-1,475

Fp

176-178°C

Storage temp.

Room temp

Solubility

H2O: 1 M at 20 °C, clear, colorless

Form

Beads

Color

White

Specific Gravity

2.13

Odor

Odorless

PH Range

13 - 14

PH

10.98(1 mM solution);11.95(10 mM solution);12.88(100 mM solution);

Water Solubility

SOLUBLE

Sensitive

Air Sensitive & Hygroscopic

Decomposition

176-178 ºC

λmax

λ: 260 nm Amax: 0.015λ: 280 nm Amax: 0.01

Merck

14,8627

Dielectric constant

57.5(25℃)

Exposure limits

TLV-TWA air 2 mg/m3 (OSHA); ceiling 2 mg/m3 (ACGIH) and 2 mg/m3/15 min (NIOSH).

Stability:

Hygroscopic

CAS DataBase Reference

1310-73-2(CAS DataBase Reference)

NIST Chemistry Reference

Sodium hydroxide(1310-73-2)

EPA Substance Registry System

Sodium hydroxide (1310-73-2)

Safety Information

PropertyValue

Hazard Codes

C,Xi

Risk Statements

36/38-35-34

Safety Statements

26-45-37/39-24/25-36/37/39

RIDADR

UN 1824 8/PG 2

WGK Germany

1

RTECS

TT2975000

F

8

TSCA

Yes

HS Code

2815 11 00

HazardClass

8

PackingGroup

II

Hazardous Substances Data

1310-73-2(Hazardous Substances Data)

Toxicity

LD orally in rabbits: 500 mg/kg (10% soln) (Fazekas)

IDLA

10 mg/m3



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